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31.
The parameters that affect the shape of the band profiles of acido‐basic compounds under moderately overloaded conditions (sample size less than 500 nmol for a conventional column) in RPLC are discussed. Only analytes that have a single pKa are considered. In the buffer mobile phase used for their elution, their dissociation may, under certain conditions, cause a significant pH perturbation during the passage of the band. Two consecutive injections (3.3 and 10 μL) of each one of three sample solutions (0.5, 5, and 50 mM) of ten compounds were injected on five C18‐bonded packing materials, including the 5 μm Xterra‐C18 (121 Å), 5 μm Gemini‐C18 (110 Å), 5 μm Luna‐C18(2) (93 Å), 3.5 μm Extend‐C18 (80 Å), and 2.7 μm Halo‐C18 (90 Å). The mobile phase was an aqueous solution of methanol buffered at a constant WWpH of 6, with a phosphate buffer. The total concentration of the phosphate groups was constant at 50 mM. The methanol concentration was adjusted to keep all the retention factors between 1 and 10. The compounds injected were phenol, caffeine, 3‐phenyl 1‐propanol, 2‐phenyl butyric acid, amphetamine, aniline, benzylamine, p‐toluidine, procainamidium chloride, and propranololium chloride. Depending on the relative values of the analyte pKa and the buffer solution pH, these analytes elute as the neutral, the cationic, or the anionic species. The influence of structural parameters such as the charge, the size, and the hydrophobicity of the analytes on the shape of its overloaded band profile is discussed. Simple but general rules predict these shapes. An original adsorption model is proposed that accounts for the unusual peak shapes observed when the analyte is partially dissociated in the buffer solution during its elution. 相似文献
32.
用Alhassid与Levine所提出的动力学李代数的方法(简称A-L理论),研究了含有二级非简谐的共线散射体系A+BC的平-振能量传递问题,计算了散射过程含有主要动力学参量的跃迁矩阵和跃迁几率的解析表示式. 相似文献
33.
We find a minimal system of generators and a homogeneous system of parameters for the algebra of invariants of three matrices of third order over a field of an arbitrary characteristic. 相似文献
34.
In this paper an extension of the (r|X
p
)-medianoid on networks introduced by Hakimi (1983) is studied. In this extension the customer considers not only the distance
but some characteristics of the facilities such as store size, quality of service and parking space. A new firm wants to establishr new facilities which have to compete with thep facilities that already exist in the market. The entry firm wants to find their locations and characteristics to maximize
profits. Three different customer choice rules (binary, partially binary and proportional preferences) are considered. Some
discretization results are obtained and a resolution procedure is proposed. The problem is solved combining a global search
algorithm based on a branch and bound procedure with some combinatorial heuristics (greedy, interchange, and tabu search).
Some computational experiences are presented.
Partially supported by Ministerio de Ciencia y Tecnología (Spain) and FEDER, grant BFM2002-04525-C02-01. 相似文献
35.
Complexes of adenine, AdH, with cobalt, nickel and copper chlorides were prepared and their thermodynamic functions were determined.
The complexing processes are endothermic in nature. The thermal behaviour of complexes was followed up by using TG and DTA
analyses. The stoichiometry of thermal decomposition of the investigated complexes was suggested.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
36.
I. Capek J. Chudej S. Janí
kov 《Journal of polymer science. Part A, Polymer chemistry》2003,41(6):804-820
The sterically stabilized emulsion polymerization of styrene initiated by a water‐soluble initiator at different temperatures has been investigated. The rate of polymerization (Rp) versus conversion curve shows the two non‐stationary‐rate intervals typical for the polymerization proceeding under non‐stationary‐state conditions. The shape of the Rp versus conversion curve results from two opposite effects—the increased number of particles and the decreased monomer concentration at reaction loci as the polymerization advances. At elevated temperatures the monomer emulsion equilibrates to a two‐phase or three‐phase system. The upper phase is transparent (monomer), and the lower one is blue colored, typical for microemulsion. After stirring such a multiphase system and initiation of polymerization, the initial coarse polymer emulsion was formed. The average size of monomer/polymer particles strongly decreased up to about 40% conversion and then leveled off. The initial large particles are assumed to be highly monomer‐swollen particles formed by the heteroagglomeration of unstable polymer particles and monomer droplets. The size of the “highly monomer” swollen particles continuously decreases with conversion, and they merge with the growing particles at about 40–50% conversion. The monomer droplets and/or large highly monomer‐swollen polymer particles also serve as a reservoir of monomer and emulsifier. The continuous release of nonionic (hydrophobic) emulsifier from the monomer phase increases the colloidal stability of primary particles and the number of polymer particles, that is, the particle nucleation is shifted to the higher conversion region. Variations of the square and cube of the mean droplet radius with aging time indicate that neither the coalescence nor the Ostwald ripening is the main driving force for the droplet instability. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 804–820, 2003 相似文献
37.
Nicholas I. M. Gould Dominique Orban Annick Sartenaer Phillipe L. Toint 《4OR: A Quarterly Journal of Operations Research》2005,3(3):227-241
In this paper, we examine the sensitivity of trust-region algorithms on the parameters related to the step acceptance and
update of the trust region. We show, in the context of unconstrained programming, that the numerical efficiency of these algorithms
can easily be improved by choosing appropriate parameters. Recommended ranges of values for these parameters are exhibited
on the basis of extensive numerical tests.
MSC classification:
65K05, 90C26, 90C30 相似文献
38.
Let R be a local ring and let (x
1, …, x
r) be part of a system of parameters of a finitely generated R-module M, where r < dimR
M. We will show that if (y
1, …, y
r) is part of a reducing system of parameters of M with (y
1, …, y
r) M = (x
1, …, x
r) M then (x
1, …, x
r) is already reducing. Moreover, there is such a part of a reducing system of parameters of M iff for all primes P ε Supp M ∩ V
R(x
1, …, x
r) with dimR
R/P = dimR
M − r the localization M
P of M at P is an r-dimensional Cohen-Macaulay module over R
P.
Furthermore, we will show that M is a Cohen-Macaulay module iff y
d is a non zero divisor on M/(y
1, …, y
d−1) M, where (y
1, …, y
d) is a reducing system of parameters of M (d:= dimR
M). 相似文献
39.
本文利用^1HNMR,UV-Vis方法,研究了t-BuNO二聚体在有机溶剂及水溶液中的裂解反应产物,分析了其反应的动力学,提出了在非极性的有机相中t-BuNO二聚体为均裂反应,而在极性的水相中为均裂和异裂同时进行的竞争反应。 相似文献
40.
A multiparameter boundary-value problem of fresh infiltration water seepage in a drained fringe above quiescent saline water is solved in the direct statement and studied in detail. 相似文献